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ISO/CD 20122

Vegetable oils — Determination of mineral oil saturated hydrocarbons (MOSH) and aromatic hydrocarbons (MOAH) with online coupled HPLC-GC-FID analysis — Method for low limit of quantification

General information

30.99     Feb 20, 2023

ISO

ISO/TC 34/SC 11

International Standard

67.200.10  

Scope

This International standard method specifies a procedure for the determination of saturated and aromatic hydrocarbons (from C10 to C50) in vegetable fats and oils using the online-coupled HPLC-GC-FID. This standard is not intended to be applied to other matrices.
The method can be used for the analysis of mineral oil saturated hydrocarbons (MOSH) and/or mineral oil aromatic hydrocarbons (MOAH).
According to the results of the interlaboratory studies, the method has been proven suitable for MOSH mass concentrations above 3 mg/kg and MOAH mass concentrations above 2 mg/kg.
In case of suspected interferences, the fossil origin of the MOSH and MOAH fraction can be verified by examination by GC⨯GC-MS.
An alternative method for the epoxidation of the MOAH fraction (performic acid epoxidation) is proposed in Annex C. This alternative method provides comparable results to the ethanolic epoxidation of the MOAH fraction described in 8.5. This alternative method for epoxidation has proven to be efficient for samples with a high amount of interferences in the MOAH fraction (e.g. tropical oils).

Life cycle

NOW

IN_DEVELOPMENT
ISO/CD 20122
30.99 CD approved for registration as DIS
Feb 20, 2023

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